Many or all of the products featured in this review are from our partners who compensate us. We believe in honesty of relationship, opinion, and identity. Sometimes I just need that one shot and being able to grab it, or quickly and easily "rip it" from the internet is such a blessing.ĭisclaimer: Our articles strive to abide by all FTC Guidelines. With the rise of apps like Instagram, Facebook and especially TikTok, there is an overwhelming amount, and regardless of what you may need it for, I guarantee, it's out there.Īs a film editor, I'm constantly needing to source from the web for news-clips, Behind- The-Scenes, random videos about Vikings, and an endless list of other things I can't remember right now. These days, it's not just YouTube that has interesting, often useful content. (*cough*detention*cough*) That's where YouTube converters come into play. Problem is, you probably have school, or a job, and a life that keeps you on the go, so who has time to sit and watch videos beyond the occasional doctor's visit? However, this isn't always a bad thing - doctor's office waiting rooms, the DMV, amiright?Įndlessly fascinating videos about every subject imaginable, and it's right at your fingertips. It's like falling down a rabbit hole that eats time like a 5-year-old eats gummy worms. If you haven't discovered the art of converting YouTube to MP3's yet, you're missing out. Please keep reading to see more detailed reviews. (Photo : Best YouTube To MP3 Converters Ranked & Reviewed) Top 3 YouTube to MP3 Converters for 2023
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But this is not the only effect we have to take into account. Thus, the attraction to the nucleus is weaker and the energy associated with the orbital is higher (less stabilized). As the principal quantum number, n, increases, the size of the orbital increases and the electrons spend more time farther from the nucleus. The filling order is based on observed experimental results, and has been confirmed by theoretical calculations. Thus, many students find it confusing that, for example, the 5 p orbitals fill immediately after the 4 d, and immediately before the 6 s. Such overlaps continue to occur frequently as we move up the chart.įigure 6.24 Generalized energy-level diagram for atomic orbitals in an atom with two or more electrons (not to scale).Įlectrons in successive atoms on the periodic table tend to fill low-energy orbitals first. The 3 d orbital is higher in energy than the 4 s orbital. However, this pattern does not hold for larger atoms. The energy increases as we move up to the 2 s and then 2 p, 3 s, and 3 p orbitals, showing that the increasing n value has more influence on energy than the increasing l value for small atoms. The 1 s orbital at the bottom of the diagram is the orbital with electrons of lowest energy. Figure 6.24 depicts how these two trends in increasing energy relate. In any atom with two or more electrons, the repulsion between the electrons makes energies of subshells with different values of l differ so that the energy of the orbitals increases within a shell in the order s < p < d < f. The energy of atomic orbitals increases as the principal quantum number, n, increases. The specific arrangement of electrons in orbitals of an atom determines many of the chemical properties of that atom. This allows us to determine which orbitals are occupied by electrons in each atom. Having introduced the basics of atomic structure and quantum mechanics, we can use our understanding of quantum numbers to determine how atomic orbitals relate to one another. Relate electron configurations to element classifications in the periodic table.Identify and explain exceptions to predicted electron configurations for atoms and ions.Derive the predicted ground-state electron configurations of atoms.(This isotope is known as “carbon-12” as will be discussed later in this chapter.By the end of this section, you will be able to: Since 1961, it has been defined with regard to the most abundant isotope of carbon, atoms of which are assigned masses of exactly 12 amu. The amu was originally defined based on hydrogen, the lightest element, then later in terms of oxygen. When describing the properties of tiny objects such as atoms, we use appropriately small units of measure, such as the atomic mass unit (amu) and the fundamental unit of charge (e). For example, a carbon atom weighs less than 2 × 10 - 23 g, and an electron has a charge of less than 2 × 10 - 19 C (coulomb). (credit middle: modification of work by “babyknight”/Wikimedia Commons credit right: modification of work by Paxson Woelber)Ītoms-and the protons, neutrons, and electrons that compose them-are extremely small. For a perspective about their relative sizes, consider this: If the nucleus were the size of a blueberry, the atom would be about the size of a football stadium ( Figure 2.3.1).įigure 2.3.1 If an atom could be expanded to the size of a football stadium, the nucleus would be the size of a single blueberry. The diameter of an atom is on the order of 10 - 10 m, whereas the diameter of the nucleus is roughly 10 - 15 m-about 100,000 times smaller. The nucleus contains the majority of an atom’s mass because protons and neutrons are much heavier than electrons, whereas electrons occupy almost all of an atom’s volume. It was learned that an atom contains a very small nucleus composed of positively charged protons and uncharged neutrons, surrounded by a much larger volume of space containing negatively charged electrons. The development of modern atomic theory revealed much about the inner structure of atoms.
As with pants, underwear comes in regular and low rise. In this case your preference may depend more on the type of pants you wear and less on your body. There’s also rise and inseam to consider. We’ve also listed the full range of sizes for each pair below. Where possible, we’ve included these details to help you find your perfect fit. And some brands are known for baggier or slimmer cuts. Boxer briefs designed for working out will fit tighter than those meant for daily wear. Within any category, however, there will be variations on cut, seam placement, and level of compression. Boxers are the loosest, which lots of men find comfortable but makes them more likely to bunch up under your pants. Below you’ll find their recommendations for the best options in every category based on fit, comfort, and style.Īmong the three main styles of men’s underwear, briefs provide the most support, but they can sometimes feel restrictive. To assist with that little bit of self-reflection, and to find a bunch of underwear worthy of your top drawer, we talked to stylists, fitness professionals, and other discerning folks about the underwear they love most. Since you often can’t return underwear once you’ve tried it on, it’s helpful to decide where you fall on the briefs-to-boxers continuum before you buy. While all that newness is exciting, you’ll need to know a bit about your own preferences before you stock up. And over the last decade, a host of direct-to-consumer brands have attempted to reimagine men’s underwear, creating a wealth of choice. In my experience, both as a former style writer for GQ and from years of conversations with friends, brothers, and significant others, most men feel just as strongly about the way their underwear fits as they do about how it looks. Some men feel best in underwear that lifts and supports, while others prefer more room for their bits to breathe. But those words mean different things to different people. If you're eager to replenish your supply-or overhaul your underwear drawer entirely-these are the only names you need to know.Much like socks and other wardrobe basics, the best men’s underwear should be comfortable, durable, and flattering. No matter your preferences, the best men's underwear brands are up to the task. So to help you make sense of the mind-boggling array of options, we went deep on all the underwear worth your time-from high end versions you'll genuinely consider washing by hand to ultra-cheap undies you can order by the multipack when the laundry machine threatens to go kaput. Intrigued by lofty-sounding fabrics like micromodal or breathable elastane blends? There's plenty of brands that'd be thrilled to hear it.įrankly, it can all get a little overwhelming. Looking for a classic pair of supima cotton boxer shorts, or a stretchy pair of moisture-wicking, spandex-enhanced boxer briefs? You won't have to look far. Because right now the market is crowded with choices, from wily upstarts promising to solve all your chafing problems to heritage labels touting anti-bunching formulas they've perfected over decades of rigorous trial and error. The underwear business isn't exactly trend-oriented, which makes the process of hunting down a new pair mercifully straightforward-if not especially exciting.īut it's one worth taking seriously. But unless you're really desperate for a fleeting serotonin hit, shopping for underwear isn't all that fun. The best men's underwear brands make up the foundations of every well-rounded wardrobe. If you need a reminder of what foods fall into each category, save this handy infographic to your camera roll. working out the best macros for fat loss) can help you lose body fat, maintain your weight or help with gaining weight safely depending on whether you're eating above or below the amount you're burning each day. The way you tinker with your macros (e.g. 'A macro' or 'macros' are abbreviations of the word 'macronutrient' and refer to the three main nutrient groups humans need. OK, so first things first: you definitely know more than you think. Macro calculator basics: what are macros and how do you use a weight loss calculator? All you need to do is scroll on and learn how to get to grips with the weight loss calculator. Whether you're looking for the best macros for fat loss or simply want more clarity around how many calories you should be eating and where they should be coming from, we've got your back. step-by-step instructions to hitting your macro goal bang on every day.the difference between calorie and macro weight loss calculators.how to calculate macros for weight loss.how to use a weight loss calculator AKA a macro calculator.Here, you'll find your macros and weight loss calculator cheat sheet with everything you need to know about macros, including: We're here to change that, by letting you into the ultimate macro calculation formula. Curious as to why you need a macro calculator in your life? Well, there are so many reasons why macros matter, from supporting your hormone health to boosting fat loss and helping you correctly fuel your fitness with a good balance of carbs, fats and protein.īut as a nutrition novice or someone without the macro-know-how, it can seem like a lot of maths without much clarity. Lape is the youngest of the five finalists at 16 years old. One of these five finalists is Grass Lake High School sophomore Lape, who quickly rose to fame over the last several months as a popular contestant of 'The Voice' under celebrity coach Blake Shelton. This is the second-to-last episode of the season where five finalists will perform live, each in hopes of swaying the public vote in their favor one last time. A big thanks to the Michigan Theatre for partnering with us on this endeavor.” “McKibbin Media Group has been following Brayden all along, like the rest of the community, so we’re excited to host this special watch party for him in his final performance. “Brayden Lape’s rise in the show to The Voice finals has been so exciting,” MMG president and owner Katina McKibbin said. The station will also be accepting donations of non-perishable food items for the Jackson Community Food Pantry as well as new, unwrapped toys for Toys for Tots. Admission is free, but donations to the theatre are welcome. Doors open at 7:00 p.m., K105.3 will play Brayden Lape trivia with the audience and give away prizes beginning at 7:30 p.m., and the episode will begin airing at 8:00 p.m. The viewing party will take place at the Michigan Theatre of Jackson, 124 N. But heres how he got 'Coach parents' in both Shelton and Gwen Stefani. Lape is a 16-year old singer from Grass Lake, just outside of Jackson. Brayden Lapes Blind Audition on 'The Voice' Season 22, Episode 2 earned a chair turn from Blake Shelton. Brayden LapeHand It to Ya 2023 Brayden LapeReleased on: Producer: Nate DodgeProducer.McKibbin Media Group's WKHM-FM (K105.3) (Jackson) is partnering with the Michigan Theatre of Jackson to host a free viewing party for Brayden Lape's final performance on NBC's 'The Voice' this Monday night (12/12). Provided to YouTube by Symphonic DistributionHand It To Ya It's never divulged how Vanny managed to accomplish this, but it stands to reason that decommissioning Bonnie could potentially be a part of the process. By the time Gregory reaches the walking corpse, he's back in a physical form, making life difficult as he attempts to mind-control Freddy and finish you off. As those who've completed the True Ending will know, Vanny has seemingly been resurrecting Springtrap (AKA William Afton) beneath the Pizzaplex. The second theory is that Security Breach's main villain is the reason Bonnie is no longer wandering the Pizzaplex. Things get extra juicy when you find out that the blue rabbit was last seen heading into Monty Golf before his absence. The manager writing the messages muses that Monty could become even bigger than Bonnie through his new role. This message – titled "Understudy" – reveals that Monty took over the role of bass player from Bonnie after he disappeared. The entrance is just outside the animatronics' green rooms. In terms of the messages, you'll find one near the stairs to the security room above the stage. The idea comes through several messages scattered throughout the Pizzaplex and the post-credits scene following the ending where Freddy and Gregory steal a van. The first is that Bonnie was actually taken down by Monty Gator. Warning, there are major spoilers ahead for two of the game's main endings. So, where is he? Well, it seems there are two solid theories as to what happened to Bonnie. In short, Bonnie's been away for a while and it doesn't seem like he's coming back any time soon. And, just in case you figured he might just be off receiving maintenance, the "Re-Theme" message claims that management is pushing for a rebranding of Bonnie Bowl as guests are asking too many questions about the missing character ( you can see the message above). Bonnie's evidently been gone a while, as Freddy even notes that he now avoids Bonnie Bowl as he misses the blue bunny so much. The large bowling alley is loaded with references to the character, although he's nowhere to be found within. You can visit the locale during the 04:00 AM - Fazer Blast mission, with Gregory needing to head there to find the Monty Mystery Mix. Not only did Bonnie play bass in the Freddy Fazbear's Mega Pizzaplex band alongside Freddy, Roxy and Chica, but he also had his very own section of the building, with Bonnie Bowl residing on the third floor. Will you be able to escape from Freddy Fazbear's Mega Pizzaplex and learn the truth about this cursed place? Read moreNow, the first thing to note about Bonnie's disappearance is that he used to be a huge part of the mall's main attractions. Hide or outrun them, but whatever your strategy is, be ready to adapt to any surprises because anything can happen in Five Nights at Freddy's: Security Breach. You will need to be creative and make use of all the items and tools at your disposal to distract and fool your pursuers. Freddy Fazbear himself will prove to be a valuable ally in this adventure, but only by making use of your wits will you be able to escape alive. Explore the different attractions in Freddy Fazbear's Mega Pizzaplex and uncover the secrets of this haunted place while you are trying to escape from the nightmarish creatures that will hunt you down. Meet iconic characters from the series like Glamrock Chica, Roxanne Wolf, Montgomery Gator, and Vanessa in an epic adventure that will keep you on the verge of collapsing from fear with every step. This youngster is about to live the most terrifying experience he could have dreamed of inside a supposedly recreational place that is home to nightmarish creatures. Five Nights at Freddy's: Security Breach is a new installment in the popular horror series that puts you in the shoes of Gregory. Freddy Fazbear's Mega Pizzaplex is not a welcoming place for intruders, especially at night, when the animatronics inside the facilities start hunting any trespassers. With the exam’s time limit, you will only have 2-3 minutes per question therefore, spending less time on problems you’re comfortable with will give you more time to work on the more challenging questions. When it comes to multiple-choice questions, you should first skim through all the questions and note problems you struggle with to come back later. We will first discuss multiple-choice questions in the paper exam. Now, let’s move on to the tips to nail the AP Calculus BC exam! Questions include at least two questions that incorporate a real-world context or scenario into the question.Questions include various types of functions and function representations and a roughly equal mix of procedural and conceptual tasks.Part B: 4 problems | Graphing calculator not permitted on the paper exam questions on the digital exam will be written such that calculator use would not help answer the question (33.3%).Part A: 2 problems | Graphing calculator required (16.7%).Questions include analytical, graphical, tabular, and verbal types of representations.Questions include algebraic, exponential, logarithmic, trigonometric, and general types of functions.Part B: 15 questions 45 minutes (graphing calculator required).Part A: 30 questions 60 minutes (calculator not permitted). Section 1 – 45 multiple choice questions have two parts: The 2022 AP Exams will be administered in schools as paper-and-pencil* exams over two weeks in May: May 2–6 and May 9–13. Not that I dropped the Duo 2 - it's too expensive to be careless with - and not that the 'Bumper' set here would necessarily be guaranteed to save the device on impact from shoulder height onto concrete, but every other metal-and-glass smartphone I've owned in recent times has been sheathed in TPU and I don't feel comfortable without a soft-touch rubber or TPU layer for my fingers to grip. Using the Duo 2 'naked' for its first week with me, carrying it around day to day, the need for something grippy and protective along its edges became more and more apparent. So, on with the principal slim-line 'Bumper'. But if the pen is for you then note that you can experiment (as I've done) with any old Surface Pen, and then you know whether you'd use the Slim Pen with official cover. Plus having a whole extra pen (and pen cover) on the front of the super-slim Duo 2 kind of defeats the point and makes the device thicker and more awkward - plus you can't fully fold the phone back onto its (already) angled camera island. My handwriting is appalling, and when I do want to 'ring' something on-screen then a finger is faster and easier. It's probably just me - I find I'm happy with my fingers and rarely need absolute precision. The Surface Duo 2 is not only compatible with all the Surface Pens (I have one here, from my Surface Go, and it works perfectly), there's even a dedicated (but relatively bulky) Surface (Slim pen) Duo 2 Pen Cover that attaches and charges a pen. But just as with the original Samsung Galaxy Notes back in the day (I had several), I try the pen functions and think they're cool but then find myself hardly ever using them again. Happy New Year!īefore heading into the review as such, I should explain why I'm not reviewing the 'Bumper's chunkier cousin accessory. Starting with the crazily priced but ultimately, dare I say, essential, official Duo 2 Bumper. With a Duo 2 now permanently at 'All About' Towers, and in addition to software features, I'm going to be reviewing some of the accessories available for this unique dual-screened smartphone/tablet. Leaving aside the whole 'started on Windows' back story (hence 'Surface Phone', its longed-for name for so long), the Surface Duo arrived with Android on board and we now have the Android 11-running Surface Duo 2, which I reviewed here two months ago. When you click on the show’s title, you’ll be taken to another page where you’ll find a review, ratings, information about when the show premiered and ended, as well as information about the show’s genre. Children can also easily access this cartoon streaming website. Toonova is another website similar to KissCartoon, with a clean interface and an excellent user experience. Additionally, it provides multiple players in the event that one player is unavailable.įeatures include the ability to watch popular Korean dramas in SD/HD video quality, as well as read comics and watch English dubbed and subbed anime.įree / no registration required 4. Additionally, you’ll see a description of the episode you’re about to watch before you click on the link. It has existed for several years without changing the domain address or name in contrast to many others, they constantly shift and relink.Įach animated film and television series is alphabetically listed. ToonGetĪnother website similar to Kisscartoon that does not frequently change domains is ToonGet. This website features an attractive design and a large selection of cartoons, ranging from timeless classics like The Tom and Jerry Show to new releases from just a few days ago.įeature: this website allows you to read comics the site is organized by category and the videos are in high definition.Ĭost: Free / Registration is not required 3. You can quickly determine which cartoon you’re watching. You can easily find new series that are available to watch. The website’s interface is simple and uncomplicated. KimCartoon is the runner-up for Kisscartoon. As the name implies, this is the place to find all Japanese anime.įeatures: Secure website, high-definition video, no advertisements Its interface is identical to that of Kisscartoon. KissAnime is most likely one of the best sites for watching anime and cartoons. Prior to your trip, you must activate adblocking software. Yes, KissCartoon is available for free, and advertisements help fund the website. Kiss Cartoon’s user interface is simple and intuitive, making it one of the most popular free streaming animation platforms. It contains a sizable library of cartoons and organizes them well, making it simple to scan for your personal favorites and view on the go. KissCartoon is one of the best cartoon streaming websites because it is elegantly designed and makes it simple for people to watch movies in high definition.Īs is the case with the majority of other streaming websites, it does not host any content on its servers. Press the “Capture” button to launch the Save To dialog box. Situate your MacBook Pro near the lecturer and tilt your screen forward or backward until the lecturer is framed within the video capture window. To use an external camera hooked up to your computer, click its name on the “Camera” pull-down menu in the bottom left corner of the Import From window. Click "Save" to save your recording.Ĭlick “File” and “New Project” in iMovie to create a new project.Įnter a name for your project in the “Project Name” field.Ĭlick an aspect ratio from the “Aspect Ratio” pull-down menu.Ĭlick the “Create” button to create your project.Ĭlick the “Open Camera Import Window” button to launch the Import From popup box, which captures video from your MacBook Pro’s built-in camera. When the lecture is over, press the spacebar to stop recording. If it does, click “Metronome” to remove the checkmark.Ĭlick the red circular “Record” button at the bottom of the GarageBand workspace to record your lecture. If the track volume meter moves from green to red, reduce the level on the Recording Level slider.Ĭlick “Control” on the main GarageBand menu and make sure that the Metronome menu item does not have a checkmark next to it. Place your MacBook Pro as close to the lecturer as possible to record a clearer signal.Ĭlick and drag the “Recording Level” slider until you achieve an adequate level that is easy to make out but does not distort the signal. To use your MacBook Pro’s built-in microphone, select “Mono 1 (Built-in Input).” To use an external microphone that you’ve attached to your MacBook Pro, click its name on the "Input Source" pull-down menu.Ĭlick “Off” on the "Monitor" pull-down menu to turn audio monitoring off, unless you plan to attach a pair of headphones to your MacBook Pro. Select your microphone using the “Input Source” pull-down menu at the bottom of the Real Instrument panel on the right of your screen. Click “Voice,” then click the “Choose” button to set up a new track.Įnter a name for your new project in the “Save As” field, and then click the “Create” button. |
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